The Organometallic Chemistry of the Transition Metals, 8/e (Hardcover)
暫譯: 過渡金屬有機金屬化學,第 8 版(精裝)
Robert H. Crabtree
- 出版商: Wiley
- 出版日期: 2026-03-23
- 售價: $2,350
- 貴賓價: 9.8 折 $2,303
- 語言: 英文
- 頁數: 576
- ISBN: 1119878519
- ISBN-13: 9781119878513
-
相關分類:
化學 Chemistry
下單後立即進貨 (約5~7天)
相關主題
商品描述
Continuing a bestselling text’s legacy of presenting our current understanding of d block organometallic compounds, their reactivity, and use in synthesis
Fully updated to reflect recent advances, the 8th edition of The Organometallic Chemistry of the Transition Metals provides readers with a comprehensive introduction to the principles and general properties of organometallic compounds as well as practical information on reaction mechanisms and detailed descriptions of contemporary applications. Maintaining the style from prior editions, the author replaces older or dated citations with current ones and changes coverage of the subject to keep the material up to date.
The new edition emphasizes such growing topics as organic applications, nanoclusters, electro- and photo-catalysis, computational studies, radical pathways, spin state effects, molecular electronics, proton coupled electron transfer, and alternative energy applications. It also adds new X-ray techniques and computational aspects that can help students design more detailed experiments.
Sample topics covered in The Organometallic Chemistry of the Transition Metals include:
- Werner complexes, the trans effect, soft versus hard ligands and metals, the crystal and ligand fields, and choice of metals
- The 18 Electron Rule, bridging ligands, electron counting in reactions, Z ligands and the oxidation state concept and its limitations
- Structure, bonding, synthesis, and reactivity of metal carbenes
- Dissociative, associative, and photochemical substitution
- Mechanisms of oxidative addition and reductive elimination
A long-time bestseller, this new edition of The Organometallic Chemistry of the Transition Metals continues to be the leading textbook on the subject for advanced undergraduate and graduate students in organic chemistry, organometallic chemistry, inorganic chemistry, and bioinorganic chemistry and practicing chemists in related fields.
商品描述(中文翻譯)
延續暢銷書的傳統,介紹目前對 d 區塊有機金屬化合物、其反應性,以及其在合成中的應用之理解
《The Organometallic Chemistry of the Transition Metals》第 8 版全面更新,反映近期的研究進展,為讀者完整介紹有機金屬化合物的原理與一般性質,以及反應機制的實務資訊和當代應用的詳細說明。本版延續前幾版的寫作風格,以最新文獻取代較舊或已過時的引文,並調整主題內容,使教材持續符合最新發展。
新版特別強調日益受到重視的主題,包括有機合成應用、奈米團簇、電催化與光催化、計算研究、自由基反應途徑、自旋態效應、分子電子學、質子耦合電子轉移,以及替代能源應用。本版也新增 X 光技術與計算相關內容,協助學生設計更為詳盡的實驗。
《The Organometallic Chemistry of the Transition Metals》涵蓋的主題包括:
• Werner 錯合物、trans effect(反式效應)、軟性與硬性配體及金屬、晶體場與配體場,以及金屬的選擇
• 18 電子規則、橋接配體、反應中的電子計數、Z 配體,以及氧化態概念及其限制
• 金屬卡賓的結構、鍵結、合成與反應性
• 解離型、締合型與光化學取代反應
• 氧化加成與還原消除的機制
本書長期以來一直是暢銷書;新版《The Organometallic Chemistry of the Transition Metals》持續作為有機化學、有機金屬化學、無機化學與生物無機化學領域高年級大學生及研究生,以及相關領域實務化學家的權威教材。
