有機場效應晶體管--原理及半導體材料(精)

何學俠 姜輝 胡鵬

  • 出版商: 科學出版
  • 出版日期: 2026-09-01
  • 售價: $768
  • 語言: 簡體中文
  • 頁數: 157
  • ISBN: 7030840070
  • ISBN-13: 9787030840073
  • 相關分類: 半導體、材料科學 Meterials
  • 下單後立即進貨 (約4週~6週)

相關主題

商品描述

場效應晶體管(FET)是一種通過電場調控固體材料導電特性的有源器件,憑借體積小、功耗低、熱穩定性優異、無二次擊穿效應及安全工作區寬等優勢,已成為現代微電子技術的核心元件。然而,傳統無機FET在器件小型化進程中已逼近物理極限,且存在成本高、大面積制備困難等瓶頸問題。在此背景下,以有機半導體材料作為活性層的有機場效應晶體管(OFET)應運而生。自1986年首個OFET問世以來,其材料設計、器件物理和工業技術等取得顯著進展,並在柔性電子、低成本傳感等領域展現出獨特應用潛力。本書系統闡述了OFET的基礎理論與材料體系,涵蓋工作機理、半導體材料分類、界面工程、性能表征及前沿應用。全書以英文撰寫,兼顧學術深度與學科交叉性,既剖析器件物理的核心原理,亦結合材料化學與工藝學的最新成果。 本書可供高等院校材料、物理和信息等專業高年級本科生、研究生、科研人員等閱讀和參考。

目錄大綱

Preface
Chapter 1 Basic Introduction to Organic Field-Effect Transistors
1.1 Basic Principle of FET
1.2 History of Development of FET
1.3 Transistor Operation in Si MOS-FET
1.4 Fundamental Principles of OFET
1.5 A Brief History of OFET
1.6 Theoretical Bases for FET
1.6.1 Explanation of technical terms in FET
1.6.2 Theoretical background of FET
1.6.3 Evaluation of carrier injection barrier height
1.7 Characterization
1.7.1 Powder X-ray diffraction
1.7.2 Single crystal X-ray diffraction
1.7.3 Infrared spectroscopy
1.7.4 Raman spectroscopy
1.7.5 Photoluminescence spectroscopy
1.7.6 Thermo-gravimetric analysis
1.7.7 Atomic force microscopy
1.7.8 Vibrating sample magnetometer
1.8 Basic Physical Concepts
1.8.1 Electrons and holes
1.8.2 Carriers in organic semiconductors: n-type, p-type and ambipolar
1.8.3 Energy levels and energy bands
1.8.4 Metals, semiconductors, and insulators
1.8.5 Work function
1.8.6 Schottky barrier
1.8.7 Device configuration
1.9 Organic Magnets
References
Chapter 2 Organic Small Molecule Field-Effect Materials
2.1 Polycyclic Aromatic Hydrocarbons and Their Derivatives
2.2 Thiaheterocycles and Their Derivatives
2.3 Halogenated Small Molecules and Their Derivatives
2.4 Cyanated Small Molecules and Their Derivatives
2.5 Quinoid Small Molecules and Their Derivatives
2.6 Lactam/Imide Small Molecules and Their Derivatives
2.7 Main Problems for Organic Small Molecule FETs
2.7.1 Challenges in material design
2.7.2 Challenges in device performance
2.7.3 Challenges in process optimization
2.8 The Development Prospects of Small Molecule FETs
2.8.1 Design and development of new materials
2.8.2 Optimization of device structure
2.8.3 Innovation in process technology
References
Chapter 3 Conjugated Polymer Field-Effect Materials
3.1 Introduction
3.2 Basic Principles of Conjugated Polymers
3.2.1 Structure and electronic properties of conjugated polymers
3.2.2 Conjugated systems and molecular orbital theory
3.2.3 Conductivity of π-conjugated systems
3.2.4 Relationship between charge mobility and molecular structure
3.3 Conjugated Polymer Materials
3.3.1 Introduction
3.3.2 P-type conjugated polymer materials
3.3.3 N-type conjugated polymer materials
3.3.4 Bipolar conjugated polymer materials
3.3.5 Atomic substitution
3.4 Optimization of Conjugated Polymer Field-Effect Materials
3.4.1 Solution processing techniques
3.4.2 Customizing film orientation
3.4.3 Optimization of polymerization reactions
3.4.4 Polymer side-chain engineering
3.5 The Development Prospects of Conjugated Polymer Field-Effect Materials
References
Chapter 4 Charge Transfer Cocrystal Field-Effect Materials
4.1 Introduction
4.2 Basic Information of Charge Transfer Cocrystals
4.2.1 LUMO-HOMO engineering
4.2.2 Definition and theory
4.2.3 Determination of charge transfer
4.3 Method for growth of charge transfer cocrystal single crystals
4.3.1 Slow cooling method
4.3.2 Slow evaporation method
4.3.3 Vapor diffusion method
4.3.4 Liquid-liquid interface method
4.3.5 Vapor method growth of charge transfer compound single crystals
4.3.6 Print growth of charge transfer compound single crystals
4.4 Materials for Charge Transfer Cocrystals
4.4.1 TCNQ-based charge transfer cocrystals
4.4.2 PDI-based charge transfer cocrystals
4.4.3 Other types of acceptor-based charge transfer cocrystals
4.5 Summary and Prospect
References
Chapter 5 Organic Thin-Film FETs
5.1 Introduction
5.2 Organic Thin-Film FET Materials
5.2.1 P-type organic thin film semiconductor materials
5.2.2 N-type organic semiconductor materials
5.2.3 Bipolar organic semicond