Interface Engineering in Organic Field-Effect Transistors

Systematic summary of advances in developing effective methodologies of interface engineering in organic field-effect transistors, from models to experimental techniques

Interface Engineering in Organic Field-Effect Transistors covers the state of the art in organic field-effect transistors and reviews charge transport at the interfaces, device design concepts, and device fabrication processes, and gives an outlook on the development of future optoelectronic devices.

This book starts with an overview of the commonly adopted methods to obtain various semiconductor/semiconductor interfaces and charge transport mechanisms at these heterogeneous interfaces. Then, it covers the modification at the semiconductor/electrode interfaces, through which to tune the work function of electrodes as well as reveal charge injection mechanisms at the interfaces.

Charge transport physics at the semiconductor/dielectric interface are discussed in detail. The book describes the remarkable effect of SAM modification on the semiconductor film morphology and thus the electrical performance. In particular, valuable analysis of charge trapping/detrapping engineering at the interface to realize new functions are summarized.

Finally, the sensing mechanisms that occur at the semiconductor/environment interfaces of OFETs and the unique detection methods capable of interfacing organic electronics with biology are discussed.

Specific sample topics covered in Interface Engineering in Organic Field-Effect Transistors include:

• Noncovalent modification methods, charge insertion layer at the electrode surface, dielectric surface passivation methods, and covalent modification methods
• Charge transport mechanism in bulk semiconductors, influence of additives on materials' nucleation and morphology, solvent additives, and nucleation agents
• Nanoconfinement effect, enhancing the performance through semiconductor heterojunctions, planar bilayer heterostructure, ambipolar charge-transfer complex, and supramolecular arrangement of heterojunctions
• Dielectric effect in OFETs, dielectric modification to tune semiconductor morphology, surface energy control, microstructure design, solution shearing, eliminating interfacial traps, and SAM/SiO2 dielectrics

A timely resource providing the latest developments in the field and emphasizing new insights for building reliable organic electronic devices, Interface Engineering in Organic Field-Effect Transistors is essential for researchers, scientists, and other interface-related professionals in the fields of organic electronics, nanoelectronics, surface science, solar cells, and sensors.

《有機場效電晶體界面工程的系統性進展總結：從模型到實驗技術》是一本關於有機場效電晶體界面工程的專書，涵蓋了有機場效電晶體的最新技術和界面的電荷傳輸、器件設計概念、器件製造過程，並展望了未來光電器件的發展。

本書首先概述了獲得不同半導體/半導體界面和這些異質界面上的電荷傳輸機制的常用方法。然後，介紹了在半導體/電極界面上的修飾方法，通過這些方法可以調節電極的功函數，並揭示界面上的電荷注入機制。

本書詳細討論了半導體/介電質界面的電荷傳輸物理。書中描述了自組裝單分子修飾對半導體薄膜形態和電性能的顯著影響。特別是，總結了在界面上實現新功能的電荷捕獲/解捕獲工程的有價值分析。

最後，本書討論了有機場效電晶體的半導體/環境界面上發生的感測機制，以及能夠將有機電子學與生物學相結合的獨特檢測方法。

《有機場效電晶體界面工程》中具體涵蓋的主題包括：
- 非共價修飾方法、電極表面的電荷插入層、介電質表面的通過修飾方法和共價修飾方法
- 堆積半導體中的電荷傳輸機制、添加劑對材料成核和形態的影響、溶劑添加劑和成核劑
- 納米限制效應、通過半導體異質結構增強性能、平面雙層異質結構、雙極性電荷轉移複合物和異質結構的超分子排列
- 有機場效電晶體中的介電質效應、調節半導體形態的介電質修飾、表面能控制、微結構設計、溶液剪切、消除界面陷阱和自組裝單分子/二氧化矽介電質

《有機場效電晶體界面工程》是一本及時的資源，提供了該領域的最新發展，並強調了構建可靠有機電子器件的新見解。這本書對於有機電子學、納米電子學、表面科學、太陽能電池和傳感器等領域的研究人員、科學家和其他界面相關專業人士至關重要。

Xuefeng Guo received his PhD in 2004 from the Institute of Chemistry, Chinese Academy of Sciences, Beijing. From 2004 to 2007, he was a postdoctoral research scientist at the Columbia University Nanocenter. He joined the faculty as a professor under the "Peking 100-Talent" Program at Peking University in 2008.

Hongliang Chen received his PhD in 2016 from the College of Chemistry and Molecular Engineering, Peking University. From 2016 to 2018, he worked as a research scientist in Dow Chemical Company. Then, he moved to Northwestern University in Evanston and worked as a postdoctoral research fellow from 2018 to 2021. He joined Zhejiang University as an assistant professor since June 2021.

郭學峰於2004年從中國科學院化學研究所獲得博士學位。2004年至2007年期間，他在哥倫比亞大學納米中心擔任博士後研究科學家。他於2008年加入北京大學，成為“北京大學百人計劃”下的教授。

陳宏亮於2016年從北京大學化學與分子工程學院獲得博士學位。2016年至2018年期間，他在陶氏化學公司擔任研究科學家。然後，他於2018年至2021年期間轉至美國伊凡斯頓的西北大學擔任博士後研究員。他自2021年6月起加入浙江大學擔任助理教授。